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(Journal Article) |
Dalton Trans 41 (13): 3623-3626 (2012)
A fluorescence "turn-on" chemodosimeter for Cu2+ in aqueous solution based on the ion promoted oxidation.
J Li
,
Y Zeng
,
Q Hu
,
X Yu
,
J Guo
ABSTRACT
We developed a novel method for Cu2+detection based on the ion promoted oxidation reaction. ChemodosimeterL(weak fluorescence) can be oxidized into 3-benzothiazoly-7-N,N-diethylaminocoumarin (strong green fluorescence, coumarin 6) by Cu2+with high selectivity and sensitivity in HEPES (10 mM, pH = 7.4) buffer containing 50% (v/v) water–CH3CN solution.